The formula unit for iron(III) fluoride is composed of 1 Fe³⁺ ion and 3 F⁻ ions. This is because iron(III) indicates that iron has a +3 charge, and fluoride ions (F⁻) have a -1 charge. To balance the charges, one Fe³⁺ ion will combine with three F⁻ ions.
Therefore, the correct answer is:
1 Fe³⁺ ion and 3 F⁻ ions.