The correct statement about distilling a mixture of acetone and water is:
Acetone is captured and cooled.
During distillation, acetone, which has a lower boiling point (56ºC), will vaporize first as the temperature is increased. The vaporized acetone can then be captured and condensed back into a liquid. Water, with a higher boiling point (100ºC), will remain in the original container until the temperature is raised sufficiently to boil it.