Since Susan's charges are directly proportional to the number of children she is watching, we can set up a ratio to find her rate per child.
Given that Susan charges $4.50 for 3 kids, we can find her charge per child:
\[ \text{Charge per child} = \frac{$4.50}{3} = $1.50 \]
Now, to find out how much she would charge for 5 kids, we multiply the charge per child by the number of kids:
\[ \text{Charge for 5 kids} = 5 \times $1.50 = $7.50 \]
So, Susan would charge $7.50 to babysit 5 kids.