To solve the expression \( (3.4 + \sqrt{-25}) - (-\sqrt{-9}) \), we start by simplifying each square root.
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Simplify \(\sqrt{-25}\): \[ \sqrt{-25} = \sqrt{25} \cdot \sqrt{-1} = 5i \]
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Simplify \(-\sqrt{-9}\): \[ -\sqrt{-9} = -\sqrt{9} \cdot \sqrt{-1} = -3i \]
Now substitute these values back into the original expression:
\[ (3.4 + 5i) - (-3i) \]
This simplifies to:
\[ 3.4 + 5i + 3i \]
Combine the imaginary parts:
\[ 3.4 + (5i + 3i) = 3.4 + 8i \]
Thus, the final answer in the form \( a + bi \) is:
\[ \boxed{3.4 + 8i} \]