To simplify the expression \((14x^2 - 3x + 2.25) + (0.75x^2 + 2x - 14)\), we combine like terms.
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Combine the \(x^2\) terms:
\[ 14x^2 + 0.75x^2 = 14.75x^2 \]
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Combine the \(x\) terms:
\[ -3x + 2x = -1x \quad \text{(or simply -x)} \]
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Combine the constant terms:
\[ 2.25 - 14 = 2.25 - 14 = -11.75 \]
Now, putting it all together:
\[ (14x^2 - 3x + 2.25) + (0.75x^2 + 2x - 14) = 14.75x^2 - x - 11.75 \]
Thus, the simplified expression is:
\[ \boxed{14.75x^2 - x - 11.75} \]