To find the measure of an exterior angle of a regular polygon, you can use the formula:
\[ \text{Exterior Angle} = \frac{360^\circ}{n} \]
where \( n \) is the number of sides in the polygon. For a polygon with five sides (a pentagon), \( n = 5 \).
Now, substituting \( n \) into the formula:
\[ \text{Exterior Angle} = \frac{360^\circ}{5} = 72^\circ \]
Therefore, the measure of any one exterior angle of the equilateral polygon with five sides is \( 72^\circ \).