Rank the given compounds based on their relative Brønsted acidities. H-I, H-F, H-SH, H-NH2, H-CH3.

I thought it correlated with whichever element was more electronegative was also more acidic. An explanation would be much appreciated.

1 answer

It correlates from left to right on the periodic table with electronegative (i.e., HF is a stronger acid than HNH2). It correlates up and down in the periodic table with size (i.e., HI is a stronger acid than HF). So CH4 should be the weakest acid and HI should be the strongest.