Posted by Jenni on Monday, December 13, 2010 at 3:32pm.
Determine the molarity of nitrate ions in a solution prepared by mixing 25.0 mL of 0.50 M Fe(NO3)3 and 35.0 mL of 1.00 M Mg(NO3)2 Please explain fully do not know where to start?
chemistry - DrBob222, Monday, December 13, 2010 at 4:33pm
You start with the definition of molarity. M = moles/L.
moles Fe(NO3)3 = M x L = ??
moles NO3^- will be 3x that.
moles Mg(NO3)2 = M x L = ??
moles NO3^- will be 2x that.
Then M NO3^- = total moles NO3^-/total volume in L.
chemistry - Jenni..can you look again i'm still not getting it thx, Monday, December 13, 2010 at 6:24pm
(0.50)(25.0) = 12.5
(1.00)(35.0) = 35
47.5/60 = 0.79M is my answer but my book says
1.79M is the correct answer
chemistry - DrBob222, Monday, December 13, 2010 at 9:27pm
You didn't follow any of my instructions. I have typed my bolded instructions below each of your lines.
0.50)(25.0) = 12.5
moles Fe(NO3)3 = M x L = ??
moles NO3^- will be 3x that.
M x L = 0.50M x 0.025 L(not 25 mL) = 0.0125 moles Fe(NO3)3
Then nitrate is 3x that or 0.0125*3 = 0.03750 moles nitrate ion
(1.00)(35.0) = 35
moles = M x L = 1.00M x 0.0350 L (not mL) = 0.0350 moles Mg(NO3)2.
Then nitrate is twice that or
2*0.0350 = 0.0700 M in nitrate.
47.5/60 = 0.79M is my answer but my book says
M nitrate = total moles/total volume in L. (0.0375+0.0700)/0.06L = 1.79 M in nitrate.
1.79M is the correct answer
So it is
chemistry - jenni, Tuesday, December 14, 2010 at 3:43pm
so I times 0.0125 by 3 b/c of the 3 at the end of the bracket?
and I times 0.0350 by 2 b/c of the 2 at the end of the bracket?
but why because when i'm doing my molar mass i do include that last # in the molar mass so why do we times it by that #?
2 answers
The problem asks for molarity of the nitrate ion. So you determine the moles Fe(NO3)3 by M x L = 0.0125, then you multiply by 3 because there are 3 nitrate ions in 1 molecule of Fe(NO3)3. The total nitrate from the Fe(NO3)3 source then is 0.0375 moles. Next you convert M x L of Mg(NO3)2 to moles = 1.0 x 0.035 = 0.035 moles Mg(NO3)2 and we multiply that by 2 because we want to know the nitrate and not magnesium nitrate. So 0.0350 x 2 = 0.07 moles nitrate from that source. The total nitrate, then, is 0.0375 moles from the Fe(NO3)3 and 0.07 moles from the Mg(NO3)2 for a total of 0.1075 moles. The total volume is 60 mL so M = moles/L = 0.1075/0.06 = 1.79 M in NO3^-.