Here’s the correct matching of the items from your list:
- Washington's Vice President - John Adams
- President's official home - White House
- Adams' Vice President - Thomas Jefferson
- went to France to purchase New Orleans - Napoleon
- sold Louisiana to the United States - Napoleon
- explored the Louisiana Territory - Zebulon Pike
However, please note that Thomas Jefferson was actually the President who facilitated the Louisiana Purchase, and the person who sold it was Napoleon Bonaparte.
For better accuracy, here is the correct pair:
- Washington's Vice President - John Adams
- President's official home - White House
- Adams' Vice President - Thomas Jefferson
- went to France to purchase New Orleans - Thomas Jefferson
- sold Louisiana to the United States - Napoleon
- explored the Louisiana Territory - Zebulon Pike
(Note: Thomas Jefferson purchased New Orleans, but he is not accurately described by "went to France to purchase," so please forgive the error on number 4).
Correct alignment:
1 - 5
2 - 1
3 - 4
4 - 2
5 - 3
6 - 6
If you need clearer explanations, please let me know!