To find an equivalent amount for \( \frac{2}{3} \) of a cup of flour, let's analyze the options:
- \( \frac{3}{3} \) of a cup is equal to 1 cup, which is not equivalent to \( \frac{2}{3} \).
- \( \frac{1}{3} \) of a cup is less than \( \frac{2}{3} \), so it's not equivalent.
- \( \frac{5}{6} \) of a cup is greater than \( \frac{2}{3} \) (because \( \frac{5}{6} = \frac{10}{12} \) and \( \frac{2}{3} = \frac{8}{12} \)), so it is also not equivalent.
- \( \frac{46}{3} \) of a cup is much greater than \( \frac{2}{3} \).
Therefore, none of the provided options are equivalent to \( \frac{2}{3} \) of a cup of flour.