To find the perimeter of the larger hexagonal shelf, we first need to determine the perimeter of the smaller shelf.
Each side of the smaller shelf measures 5 inches, and since a hexagon has 6 sides, we can calculate the perimeter of the smaller shelf as follows:
\[ \text{Perimeter of smaller shelf} = \text{Side length} \times \text{Number of sides} = 5 \text{ inches} \times 6 = 30 \text{ inches} \]
Next, since the larger shelf is scaled up by a factor of 2, we first find the perimeter of the larger shelf by multiplying the perimeter of the smaller shelf by the scale factor:
\[ \text{Perimeter of larger shelf} = \text{Perimeter of smaller shelf} \times \text{Scale factor} = 30 \text{ inches} \times 2 = 60 \text{ inches} \]
Thus, the perimeter of the larger shelf is:
\[ \boxed{60} \text{ inches} \]