M grams of potassium hydroxide were dissolved in distilled water to make 100 cubic centimeters of solution. 50 cubic centimeters of the solution required 50 cubic centimeters of 2.0M nitric acid for complete neutralization. Calculate the mass M of potassium hydroxide

1 answer

To find the mass \( M \) of potassium hydroxide (KOH) that was dissolved, we start by analyzing the reaction and the information provided in the problem.

  1. Stoichiometry of the Reaction: The reaction between potassium hydroxide (KOH) and nitric acid (HNO₃) can be represented as:

    \[ \text{KOH (aq)} + \text{HNO}_3 \text{ (aq)} \rightarrow \text{KNO}_3 \text{ (aq)} + \text{H}_2\text{O (l)} \]

    From the balanced equation, we can see that the molar ratio of KOH to HNO₃ is 1:1.

  2. Calculating Moles of Nitric Acid: We know that 50 cubic centimeters (cc) of 2.0 M nitric acid is used for neutralization. First, we'll convert 50 cc to liters: \[ 50 , \text{cc} = 0.050 , \text{L} \]

    Now we can calculate the moles of nitric acid: \[ \text{Moles of HNO}_3 = \text{Molarity} \times \text{Volume} = 2.0 , \text{M} \times 0.050 , \text{L} = 0.1 , \text{moles} \]

  3. Calculating Moles of Potassium Hydroxide: Since the stoichiometry is 1:1, the moles of KOH reacted will also be 0.1 moles.

  4. Concentration of KOH in the Original Solution: The 100 cc (or 0.100 L) solution contains these 0.1 moles of KOH. To find the molarity of KOH in the original solution, we use: \[ \text{Molarity of KOH} = \frac{\text{moles of KOH}}{\text{volume of solution in L}} = \frac{0.1 , \text{moles}}{0.100 , \text{L}} = 1.0 , \text{M} \]

  5. Calculating Mass of KOH: The molar mass of KOH can be calculated as follows:

    • Potassium (K): 39.10 g/mol
    • Oxygen (O): 16.00 g/mol
    • Hydrogen (H): 1.01 g/mol

    \[ \text{Molar mass of KOH} = 39.10 + 16.00 + 1.01 = 56.11 , \text{g/mol} \]

    Using the molarity and the volume, we can find the mass of KOH in the solution: \[ \text{Mass of KOH} = \text{moles of KOH} \times \text{molar mass of KOH} = 0.1 , \text{moles} \times 56.11 , \text{g/mol} = 5.611 , \text{g} \]

  6. Final Result: The mass \( M \) of potassium hydroxide that was dissolved is approximately:

    \[ M \approx 5.61 , \text{grams} \]

Thus, the answer is: \[ \boxed{5.61 , \text{g}} \]