Let \( x \) be the number of comic books on each shelf initially. Since there are 5 shelves, the total number of comic books before the addition is:
\[ 5x \]
His father adds 20 comic books to the bottom shelf, making the number of books on that shelf:
\[ x + 20 \]
According to the problem, this shelf now contains 125 comic books. Therefore, we can set up the equation:
\[ x + 20 = 125 \]
To solve for \( x \), subtract 20 from both sides:
\[ x = 125 - 20 \] \[ x = 105 \]
Now that we have the number of comic books on each shelf, we can calculate the total number of comic books in the collection:
\[ \text{Total books} = 5x = 5 \times 105 \] \[ \text{Total books} = 525 \]
Thus, the total number of books in Jose's collection is:
\[ \boxed{525} \]