In the construction of a circumcircle for triangle DEF, James has already marked the intersections of arcs to find angle bisectors. The next step in the geometric construction would be to find the perpendicular bisector of one of the triangle's sides.
Specifically, he should:
Use the compass to find the perpendicular bisector for side DF.
Once he has completed the perpendicular bisectors for two sides (which he may have already started), he will be able to find the circumcenter of the triangle by determining where these perpendicular bisectors intersect. This circumcenter will serve as the center of the circumscribed circle.