To find the ratio of the perimeter of the smaller square to the larger square, we first need to calculate the perimeter of each square.
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Perimeter of the smaller square: \[ \text{Perimeter} = 4 \times \text{side length} = 4 \times 2 \text{ cm} = 8 \text{ cm} \]
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Perimeter of the larger square: \[ \text{Perimeter} = 4 \times \text{side length} = 4 \times 6 \text{ cm} = 24 \text{ cm} \]
Now we can find the ratio of the perimeter of the smaller square to the perimeter of the larger square: \[ \text{Ratio} = \frac{\text{Perimeter of smaller square}}{\text{Perimeter of larger square}} = \frac{8 \text{ cm}}{24 \text{ cm}} = \frac{8}{24} \]
To simplify the fraction: \[ \frac{8}{24} = \frac{1}{3} \]
Thus, the ratio of the perimeter of the smaller square to the larger square is: \[ \boxed{\frac{1}{3}} \]