Since ∠3 and ∠5 are vertical angles, they are equal. Therefore, the measure of ∠5 is:
\[ m∠5 = m∠3 = 67° \]
Given that ∠4 is supplementary to ∠5, we know that the sum of their measures equals 180°:
\[ m∠4 + m∠5 = 180° \]
Substituting the value of m∠5:
\[ m∠4 + 67° = 180° \]
So the equation you can write to solve for m∠4 is:
\[ m∠4 + 67° = 180° \]