To solve the question, we need to recall the relationship between sine and cosine for complementary angles.
The angles 23° and 67° are complementary angles because: \[ 23° + 67° = 90°. \]
According to the sine and cosine complementary angle identity, we have: \[ \sin(90° - \theta) = \cos(\theta). \]
This means: \[ \sin(67°) = \cos(23°). \]
Given that \( \cos(23°) = \frac{2}{3} \), we find that: \[ \sin(67°) = \frac{2}{3}. \]
So the answer is two thirds, because the angles are complementary.