The angles 23° and 67° are complementary, meaning that the sum of their measures equals 90° (23° + 67° = 90°).
According to the co-function identities, the sine of an angle is equal to the cosine of its complement:
\[ \sin(67°) = \cos(23°) \]
Given that \(\cos(23°) = \frac{2}{3}\), we can substitute that into the equation:
\[ \sin(67°) = \frac{2}{3} \]
Therefore, the answer is:
\(\frac{2}{3}\), because the angles are complementary.