This may be a limiting reagent problem. You must determine which is the limiting reagent. To do this, I usually simply calculate how much of one reagent is needed if we start with the other. For example,
8.6 L H2 will require how much O2?
8.6 x (1 mol O2/2 mols H2) = 4.3 and we have exactly 4.3; therefore, both are limiting and we have exactly the amount of each we need. Use this same procedure to determine the amount of H2O produced.
if 8.6L of H2 reacted with 4.3L of O2 at STP, what is the volume of gaseous water collected (assuming none of it condenses)? 2H2(g) + O2(g) => 2H2O(g)
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