Gallium has two naturally occurring isotopes, 69Ga and 71Ga, with masses of 68.9257amu and 70.9249amu, respectively. Calculate the percent abundances of these isotopes of gallium.

1 answer

To find the percent abundances of the isotopes of gallium (\(^{69}\text{Ga}\) and \(^{71}\text{Ga}\)), we will use the average atomic mass of gallium, which is approximately 69.723 amu. We can set up a system of equations to solve for the abundances.

Let:

  • \(x\) = the fraction of \(^{69}\text{Ga}\)
  • \(y\) = the fraction of \(^{71}\text{Ga}\)

The relations we can use are:

  1. The sum of the fractions must equal 1: \[ x + y = 1 \]

  2. The weighted average of the masses gives us the average atomic mass: \[ 68.9257x + 70.9249y = 69.723 \]

Now, we can solve these equations. From the first equation, we have: \[ y = 1 - x \]

Substituting \(y\) into the second equation: \[ 68.9257x + 70.9249(1 - x) = 69.723 \]

Expanding and simplifying: \[ 68.9257x + 70.9249 - 70.9249x = 69.723 \] \[ (68.9257 - 70.9249)x + 70.9249 = 69.723 \] \[ -1.9992x + 70.9249 = 69.723 \]

Now, isolate \(x\): \[ -1.9992x = 69.723 - 70.9249 \] \[ -1.9992x = -1.2019 \] \[ x = \frac{-1.2019}{-1.9992} \approx 0.601 \]

Now, substitute back to find \(y\): \[ y = 1 - x = 1 - 0.601 \approx 0.399 \]

Finally, we can express these abundances as percentages:

  • Percent of \(^{69}\text{Ga}\): \[ \text{Percent of }^{69}\text{Ga} = x \times 100 \approx 0.601 \times 100 \approx 60.1% \]

  • Percent of \(^{71}\text{Ga}\): \[ \text{Percent of }^{71}\text{Ga} = y \times 100 \approx 0.399 \times 100 \approx 39.9% \]

Thus, the percent abundances of the isotopes of gallium are:

  • \(^{69}\text{Ga}\): 60.1%
  • \(^{71}\text{Ga}\): 39.9%