To find the product of \( 5 - \sqrt{16} \) and \( 16 \), we first simplify \( \sqrt{16} \).
\[ \sqrt{16} = 4 \]
Now we can substitute this back into the expression:
\[ 5 - \sqrt{16} = 5 - 4 = 1 \]
Next, we multiply this result by \( 16 \):
\[ 1 \times 16 = 16 \]
Since \( 16 \) is a whole number, it is a rational number.
Therefore, the correct answer is:
16; a rational number.
(Note: The options provided in the question seem to be inconsistent with the calculation, as none match the product of \( 5 - \sqrt{16} \) and \( 16 \) which we calculated to be \( 16 \).)