Drop a piece of copper foil into a test tube containing concentrated nitric acid in a fume cupboard. Describe what happens

3 answers

When a piece of copper foil is dropped into a test tube containing concentrated nitric acid in a fume cupboard, the following reactions occur:

1. Initially, there might be no immediate visible reaction, but the copper foil starts to react with the nitric acid slowly.

2. As the copper foil reacts with the nitric acid, the solution in the test tube starts to turn blue or greenish-blue due to the formation of copper(II) nitrate. This occurs because nitric acid oxidizes the copper, converting it into its ionic form (Cu2+).

3. Simultaneously, brown-red fumes, which are nitrogen dioxide (NO2) gas, start to evolve from the test tube. Nitric acid acts as an oxidizing agent, oxidizing nitric oxide (NO) formed by the reaction of nitric acid with copper to nitrogen dioxide gas.

The overall chemical reaction can be represented as:

Cu + 4HNO3 → Cu(NO3)2 + 2NO2 + 2H2O

In this reaction, copper reacts with nitric acid to form copper(II) nitrate, nitrogen dioxide gas, and water.

It is important to conduct this reaction in a fume cupboard to ensure that any toxic fumes, such as nitrogen dioxide, are safely vented and do not pose a risk to the experimenter or the environment.
Summarize the above answers
When copper foil is dropped into concentrated nitric acid in a fume cupboard, it reacts slowly, forming a blue or greenish-blue solution due to the formation of copper(II) nitrate. Additionally, brown-red fumes of nitrogen dioxide gas are released. This reaction occurs because nitric acid oxidizes the copper, and the overall reaction can be represented as Cu + 4HNO3 → Cu(NO3)2 + 2NO2 + 2H2O. Conducting this reaction in a fume cupboard is necessary to ensure the safe venting of toxic fumes.