I would do this.
............N2O4 ==> 2NO2
initial..0.554.........0
change....-p..........+2p
equil....0.554-p.......2p
Total P @ equil = 0.770; therefore,
0.554-p+2p = 0.770 and this allows you to calculate Kp.
NO2 is injected to make Ptotal = 0.906 bar so that makes 0.906-0.770 = 0.136 bar injected.
I would make a new ICE chart with NO2 start = 0.136 + old equil pressure and N2O4 = old equil and recalculate new pressures using the Kp from the first part. You know, of course that the reaction will be shifted to the left.
Dinitrogen tetroxide decomposes according to N2O4 (g) = 2NO2 (g)
In a certain experiment, N2O4(g) at an initial pressure of 0.554 bar is introduced into an empty reaction container; after equilibrium is established, the total pressure is 0.770 bar. A quantity of NO2(g) is injected into the container and the total pressure jumps to 0.906 bar. Calculate the total pressure after equilibrium is reestablished.
I need help setting up this problem. Please help.
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