To analyze the statements:
I. Stirring slows down (decreases) rate of dissolution.
- This statement is incorrect; stirring typically increases the rate of dissolution by allowing solute particles to disperse more quickly in the solvent.
II. Grinding solids increases their surface area of contact.
- This statement is correct; grinding particles into smaller sizes increases the surface area available for dissolution.
III. Heating slows down (decreases) rate of dissolution.
- This statement is incorrect; generally, heating increases the rate of dissolution by providing energy to the particles, allowing them to break apart more easily.
IV. Grinding solids speeds up their rate of dissolution.
- This statement is correct; by increasing the surface area, grinding allows more solute to come in contact with the solvent, facilitating a quicker dissolution.
Based on the analysis:
- Statement II is correct.
- Statement IV is correct.
- Statements I and III are incorrect.
The correct response is B: II and IV.