Consider the titrtation of 25.0mL of 0.0100M Sn2+ by 0.0500M TI3+ in 1 M HCL, using Pt and Saturated Calomel Electrodes to find the endpoint.

F=96486.7 Cmol

E0 Sn4+/Sn2+ =0.15V

E0 TI3+/TI+ = 1.28

Esce = 0.241V

R=8.3141 J K Mol

(D) calculate E at the following volumes of TI3+ : 1.00mL, 2.50mL, 4.90mL, 5.00mL,5.10mL and 10.0mL

2 answers

2.4
for the titration of             50.0 mL of 0.0500 M Sn2+ after adding 10, 25 and 40 mL of 0.100 M Tl3+. Both the       analyte and the titrant are 1.0 M in HCl.