The best explanation for the difference in bond energies between Cl–Cl and Br–Br bonds is:
Bromine has more electron levels than chlorine.
This is because bromine is located lower in the periodic table than chlorine, which means it has more electron shells. This increased distance between the nucleus and the bonding electrons in bromine leads to a weaker bond compared to the Cl–Cl bond. Additionally, the larger size of bromine atoms contributes to a longer bond length, resulting in lower bond energy.