Can someone please explain why there are so many gas laws. I've been doing my homework with the appropriate formulas, but I'm confused why everyone keeps say that PV=nRT is so wonderful? You can't get the same solution by using this ONE formula, so what is so wonderful?

Is there ONE formula or must I pay close attention to the constants in the word problem?

Thanks for your help!!!

1 answer

There is one formula and you CAN get the same answer no matter which formula is used. It is PV = nRT; however, some problems don't list the moles (just P, V, and T for one set of conditions and something for another set of conditions). Therefore, to use the one formula one must solve PV = nRT for the first set of conditions, find n, then use that n with the second set of conditions and PV = nRT to find whatever the unknown is. And there is nothing wrong with that but some of us are lazy and we use (P1V1/T1) = P2V2/T2) as a shortcut which gets the correct answer with just one calculator manipulation. And those are the only two equations you need to know.
1. PV = nRT when you need to calculate n and
2. (P1V1/T1) = (P2V2/T2) when you want to take the shortcut and have the information to do so.

But what about P1V1 = P2V2 and P1/T1 = P2/T2 and V1/T1 = V2/T2 you say? Those are NOT separate formulas; they all come from (P1V2/T1) = (P2V2/T2).
Here is what you do.
If the problem lists P and V with one set and it gives P and asks for V for another set, just mentally cover up the T1 and T2 in that #2 equation. That gives you P1V1 = P2V2 and solve the unknown. Or if the problem gives a V1 and V2 and T2 and asks for T1, just cover up the P1 and P2 mentally and you have V1/T1 = V2/T2 and solve for the unknown. You get the idea. I hope this helps. It CAN be confusing but it need not be if you just remember those two and make your own for what you need.