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between butane,cis-2-butane,2-butyne,ethane and trans-2-butene which one has higher melting

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What in the world is cis-2-butane?

I looked the melting points up on the web. Assuming you meant cis-2-butENE and not cis-2-butane(I don't know what this is). I found 2-butyne to have the highest m.p. @ -32 C

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