BAYER’S TEST (Unsaturation)

1. To a clean test tube, add 1 -2 ml of the unknown organic solution
2. Measure 2ml of distilled water and add to the test tube containing the unknown solution and shake
well
3. Add 2-3 drops of the KMnO4 solution to it.
4 Observe the changes and the reaction carefully. Take note of the changes.
What are the possible results after this experiment?

1 answer

Bayer's test, also known as the permanganate test, is a classic test used to determine the presence of unsaturation (alkenes or alkynes) in organic compounds. In this test, potassium permanganate (KMnO4) acts as an oxidizing agent and will react with the double or triple bonds present in unsaturated hydrocarbons, resulting in observable changes. Here are the possible results after conducting the test:

  1. Color Change:

    • Positive Result (Unsaturation Present): The deep purple color of the KMnO4 solution will fade to brown or colorless due to the formation of manganese dioxide (MnO2) as the permanganate ions are reduced during the reaction. This indicates the presence of alkenes or alkynes in the unknown organic solution.
    • Negative Result (No Unsaturation): If no change occurs and the purple color remains, this suggests that the unknown organic compound does not have any double or triple bonds, indicating it is likely a saturated compound (such as an alkane).
  2. Formation of Precipitate:

    • The formation of a brown precipitate (MnO2) is also a sign that unsaturation is present. If a precipitate forms, it supports the conclusion that the organic compound contains carbon-carbon double bonds or triple bonds.
  3. No Reaction/Stable Solution:

    • If the solution remains purple and no precipitate forms, this confirms that no reaction has occurred, indicating the absence of unsaturation in the unknown organic compound.

In summary, a positive result indicates unsaturation (loss of purple color and possible brown precipitate), while a negative result (little or no change) suggests that the compound is saturated with no double or triple bonds.