To balance the chemical equation for the reaction between sulfuric acid (H₂SO₄) and hydroiodic acid (HI) producing dihydrogen sulfide (H₂S), iodine (I₂), and steam (H₂O), we can follow these steps:
Unbalanced equation: \[ \text{H}_2\text{SO}_4 + \text{HI} \rightarrow \text{H}_2\text{S} + \text{I}_2 + \text{H}_2\text{O} \]
Balancing the equation:
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Count the number of each type of atom on both sides of the equation:
- Left side:
- H: 2 (from H₂SO₄) + 1 (from HI) = 3
- S: 1 (from H₂SO₄)
- O: 4 (from H₂SO₄)
- I: 1 (from HI)
- Right side:
- H: 2 (from H₂S) + 2 (from H₂O) = 4
- S: 1 (from H₂S)
- I: 2 (from I₂)
- O: 1 (from H₂O)
- Left side:
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Adjust coefficients to balance the equation. Start with iodine (I) because it is present in fewer species:
- We need 2 HI for every I₂ produced, so we put a coefficient of 2 in front of HI.
\[ \text{H}_2\text{SO}_4 + 2 \text{HI} \rightarrow \text{H}_2\text{S} + \text{I}_2 + \text{H}_2\text{O} \]
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Recount atoms after adding the coefficient:
- Left side:
- H: 2 (from H₂SO₄) + 2 (from 2HI) = 4
- S: 1
- O: 4
- I: 2
- Right side:
- H: 2 (from H₂S) + 2 (from H₂O) = 4
- S: 1
- O: 1
- I: 2
- Left side:
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Count the oxygen atoms. There are 4 on the left side and 1 on the right side. We need to adjust H₂O. Since we have to account for the 4 oxygens, we can put a coefficient of 3 before H₂O.
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The equation now looks like this: \[ \text{H}_2\text{SO}_4 + 2 \text{HI} \rightarrow \text{H}_2\text{S} + \text{I}_2 + 3 \text{H}_2\text{O} \]
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Finally, check again the balance:
- Left side:
- H: 2 (H₂SO₄) + 2 (2HI) = 4, which equals 6 (2 from H₂S + 6 from 3H₂O)
- S: 1
- O: 4 (4 total)
- I: 2
- Left side:
The balanced equation would therefore be: \[ \text{H}_2\text{SO}_4 + 2 \text{HI} \rightarrow \text{H}_2\text{S} + \text{I}_2 + 2 \text{H}_2\text{O} \]
To ensure both sides balance, let's finalize our coefficients: The final balanced equation is: \[ \text{H}_2\text{SO}_4 + 4 \text{HI} \rightarrow \text{H}_2\text{S} + 2 \text{I}_2 + 2 \text{H}_2\text{O} \]
So, the final coefficients are:
- 1 for H₂SO₄
- 4 for HI
- 1 for H₂S
- 2 for I₂
- 2 for H₂O