In the formation of lithium chloride (LiCl), the bonding involves the transfer of electrons. Lithium (Li) has one valence electron, while chlorine (Cl) has seven valence electrons. To achieve a stable electronic configuration, lithium will lose its one valence electron, and chlorine will gain an electron to complete its outer shell.
Therefore, the correct statement regarding the rearrangement of valence electrons to form the ionic bond in lithium chloride is:
Electrons are transferred from the lithium atom to the chlorine atom.