Although nitrogen gas makes up 78% of the atmosphere, we can't use it because nitrogen atoms must be broken apart first.
In nature, nitrogen gas (N₂) is very stable and is not in a form that most organisms can directly use. Plants and animals need nitrogen in more reactive forms, such as ammonia (NH₃) or nitrates (NO₃⁻), which are typically made available through the processes of nitrogen fixation carried out by certain bacteria and other organisms.