To add the terms \(3\sqrt{3}\) and \(5\sqrt{3}\), we can combine them because they have the same radical part.
\[ 3\sqrt{3} + 5\sqrt{3} = (3 + 5)\sqrt{3} = 8\sqrt{3} \]
So, the correct choice is:
A. \(3\sqrt{3} + 5\sqrt{3} = 8\sqrt{3}\) (Please type an exact answer, using radicals as needed.)
The answer is \(8\sqrt{3}\).