The most helpful physical property of the sample to determine if the liquid is water is:
A. The boiling point of the liquid.
Water has a specific boiling point (100°C or 212°F at 1 atmosphere of pressure), which can be used as a definitive criterion to identify if the unknown liquid is indeed water. The other options, such as mass, color, and smell/taste, are not specific enough to definitively identify water, as many liquids can share similar characteristics.