To determine the correct statement and conclusion about sodium hydroxide based on the given information, let's analyze the situation:
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When sodium hydroxide (NaOH), a strong base, is dissolved in water, it dissociates completely to produce hydroxide ions (OH⁻).
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A pH of 12 indicates a basic solution. The relationship between pH and pOH can be established using the following equations:
- pH + pOH = 14
From this, you can calculate the pOH:
- pOH = 14 - pH
- pOH = 14 - 12 = 2
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The concentration of hydroxide ions ([OH⁻]) can be determined from the pOH. Since pOH is defined as:
- pOH = -log[OH⁻]
Rearranging gives:
- [OH⁻] = 10^(-pOH) = 10^(-2) = 0.01 M
Now let's evaluate the options provided:
- The negative log of the concentration of OH⁻ ions is 2. Sodium hydroxide is a strong acid.
- The negative log of the concentration of OH⁻ ions is 12. Sodium hydroxide is a strong acid.
- The negative log of the concentration of OH⁻ ions is 12. Sodium hydroxide is a strong base.
- The negative log of the concentration of OH⁻ ions is 12. Sodium hydroxide is a strong base.
- The negative log of the concentration of OH⁻ ions is 2. Sodium hydroxide is a strong base.
From the calculations above, we established that:
- The pOH is 2 (not 12).
- The concentration of OH⁻ ions corresponds to that pOH value, confirming that sodium hydroxide is indeed a strong base.
Therefore, the correct statement is:
"The negative log of the concentration of OH⁻ ions is 2. Sodium hydroxide is a strong base."