To determine the accurate statements regarding sodium hydroxide (NaOH) and the pH of the solution:
- The pH of the solution is given as 12.
- The relationship between pH and pOH can be defined using the equation: \[ pH + pOH = 14 \] From this we can calculate pOH: \[ pOH = 14 - pH = 14 - 12 = 2 \]
- The concentration of hydroxide ions (OH⁻) can be calculated using the pOH: \[ OH^- = 10^{-pOH} = 10^{-2} = 0.01 , \text{M} \]
- Since sodium hydroxide is a strong base, it fully dissociates in water. Therefore, the concentration of NaOH is also 0.01 M.
Now let's analyze the given options:
- The negative log of the concentration of OH– ions is 2. Sodium hydroxide is a strong base. (This is correct)
- The negative log of the concentration of OH– ions is 12. Sodium hydroxide is a strong acid. (This is incorrect)
- The negative log of the concentration of OH– ions is 12. Sodium hydroxide is a strong base. (This is incorrect)
- The negative log of the concentration of OH– ions is 2. Sodium hydroxide is a strong acid. (This is incorrect)
The correct statement is: The negative log of the concentration of OH– ions is 2. Sodium hydroxide is a strong base.