The ideal response would likely be: There is not enough information to determine whether this is an appropriate, random sample for the population in this scenario.
While random selection is a key factor in reducing bias, the effectiveness of the trial may depend on including a representative sample of the population that experiences migraines. Characteristics such as age, gender, and possibly other factors can influence the prevalence and severity of migraine headaches. Therefore, without knowing more about the demographics of the selected volunteers in relation to the general population of migraine sufferers, it's difficult to conclude whether the sample is appropriate.