A closed bottle contains a solution of 5.0% by mass acetone [(CH3)2CO] in water. Calculate the vapour pressure (in kPa) of this solution at 25oC. The vapour pressure of pure water at 25oC is 3.17 kPa and that of pure acetone is 30.7 kPa.

1 answer

If you assume this is an ideal solution. Take 100 g solution.
mass acetone = 5g
mols acetone = 5/molar mass = ?

mass H2O = 95 g
mols H2O = 95/molar mass H2O = ?

total mols = mols acetone = mols H2O = ?

Xacetone = mols fraction acetone = nacetone/total mols
xH2O = nH2O/total mols.

pacetone = Xacetone*Poacetone
pH2O = XH2O*PoH2O

Total P = pacetone + pH2O