The item from the list that will have a chemical reaction with iodine is a. cornstarch.
When iodine comes into contact with cornstarch, it forms a blue-black complex due to the formation of iodine-starch complex, which is a characteristic reaction used to indicate the presence of starch. The other items listed (baking soda, salt, and powdered sugar) do not produce a color change upon reacting with iodine in the same manner.