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The reaction of 8.7 grams of fluorine with excess chlorine produced 3.9 grams of ClF3. What percent yield of ClF3 was obtained?...Question
The reaction of 5.3 grams of fluorine with
excess chlorine produced 4.6 grams of ClF3. What percent yield of ClF3 was obtained?
Answer in units of %
excess chlorine produced 4.6 grams of ClF3. What percent yield of ClF3 was obtained?
Answer in units of %
Answers
Graham
Yield = practical/theoretical
Given:
Practical mass: Pm{ClF3} = 4.6g
Reactant mass: m{F2} = 5.3g
The equation: 3 F2 + Cl2 = 2 ClF3
Lookup the Molecular Weights:
w{F2} = 37.99680650 ± 0.00000002 g/mol
w{ClF3} = 92.4484 ± 0.0001 g/mol
So theoretically, the mass of chlorine triflouride is:
Tm{ClF3} = (2/3) m{F2}w{ClF3}/w{F2}
Therefore:
Yield = Pm{ClF3}/Tm{ClF3}
= (3/2) Pm{ClF3} w{F2} /(m{F2} w{ClF3})
= (3/2)*4.6*37.99680650/(5.3*92.4484)
= 53.5%
Given:
Practical mass: Pm{ClF3} = 4.6g
Reactant mass: m{F2} = 5.3g
The equation: 3 F2 + Cl2 = 2 ClF3
Lookup the Molecular Weights:
w{F2} = 37.99680650 ± 0.00000002 g/mol
w{ClF3} = 92.4484 ± 0.0001 g/mol
So theoretically, the mass of chlorine triflouride is:
Tm{ClF3} = (2/3) m{F2}w{ClF3}/w{F2}
Therefore:
Yield = Pm{ClF3}/Tm{ClF3}
= (3/2) Pm{ClF3} w{F2} /(m{F2} w{ClF3})
= (3/2)*4.6*37.99680650/(5.3*92.4484)
= 53.5%