Question

A typical buffer used by biochemists is called Tris, which can be depicted as R3N. A buffer that is prepared by mixing 500ml of .05M R3N with 500ml of .05MR3NHCl at 25 C has a pH of 8.40. If this same buffer is placed in a cold room at 4 C the pH increases to 9.2. From this data determine the delta Hrxn for R3NH^+(aq) --> R3N(aq)+H^+(aq)

Nov 17, 2011

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