Asked by Kris

how do i calculate the [OH-] and [Ca2+] using the equivalence point? Then I have to calculate the Ksp for calcium hydroxide.

Answers

Answered by DrBob222
It is easier if you have some numbers to work with. Also some explanation of what you are doing would help.
Answered by Kris
Well the equivalence point in volume is 11.3 mL and the pH is 7.45.

We did a titration lab of calcium hydroxide. Ksp of calcium hydroxide
Answered by DrBob222
Ca(OH)2 ==> Ca^2+ + 2OH^-

Ksp = (Ca^2+)(OH^-)^2

Assuming you titrated with HCl, the equation is
Ca(OH)2 + 2HCl ==> CaCl2 + 2H2O
So at the equivalence point the pH = 7.45. I would convert to pOH (pH + pOH = pKw = 14), then pOH = -log(OH^-) to obtain (OH^-). For Ca^2+, that will be 1/2 moles HCl used to get to the equivalence point; so (MHCl x LHCl)/2 = (Ca^2+)
Answered by Kris
Kw would be 1.0x10^-15 right? Cant quite remember the exponent
Answered by Kris
I don't understand this part

(pH + pOH = pKw = 14)

PKw is equal to 14?
Answered by Kris
Actually forget that. When you say 1/2 the moles of HCl, do you mean take half of the moles of HCl used originally? Times the volume of equivalence point?
Answered by Kris
I tried doing it and got 1.96x10^-13...I dunno if it's correct
Answered by Kris
1.96x10^-16 *
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