Question
Sucrose hydrolyzes into glucose and fructose. The hydrolysis is a first order reaction. the half life for the hydrolysis of sucrose is 64.2min at 25C. How many grams fo sucrose in 1.25L of a 0.389M solution are hydrolyzed in 1.73hrs?
I started off by finding k the constant
t1/2=0.693/k
64.2min=0.693/k
k=0.01079
I'm not sure what to do after this
I converted the 64.2min into hrs and got k as 0.6477
I started off by finding k the constant
t1/2=0.693/k
64.2min=0.693/k
k=0.01079
I'm not sure what to do after this
I converted the 64.2min into hrs and got k as 0.6477
Answers
Since you want the answer in hours I would use the k in the hour units.
How many grams do you have in the solution? 1.25L x 0.389 moles/L x 342.3 grams/mole = ?? (about 166 but that is approximate).
ln(No/N) = kt
I would substitute 166 (or the actual number you obtain) for No, solve for N, and substitute 1.73 for t and the k you have in hr^-1. Solve for N which will be the grams REMAINING after 1.73 hours. That subtracted from the number of grams initially should be the amount decomposed.
How many grams do you have in the solution? 1.25L x 0.389 moles/L x 342.3 grams/mole = ?? (about 166 but that is approximate).
ln(No/N) = kt
I would substitute 166 (or the actual number you obtain) for No, solve for N, and substitute 1.73 for t and the k you have in hr^-1. Solve for N which will be the grams REMAINING after 1.73 hours. That subtracted from the number of grams initially should be the amount decomposed.
ln166.44-lnx=0.64766*1.73
-lnx=1.120-ln166.44
lnx=3.9942
x=E^3.9942
=54.27
166.54-54.27=112g
-lnx=1.120-ln166.44
lnx=3.9942
x=E^3.9942
=54.27
166.54-54.27=112g
That looks good to me.
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