why should samples be weighed rather than measured volumetrically when determining the acetic acidin vinegar

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1. why should samples be weighed rather than measured volumetrically when determining the percent acetic acid in vineger
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3. Could you help me find some websites that can tell me what the ingredients are in vinegar.http://en.wikipedia.org/wiki/Vinegar
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4. Vinegar is a solution of acetic acid, CH3COOH, dissolved in water. A 4.69 g sample of vinegar was neutralized by 32.97 mL of
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