Asked by ny
What is the relationship between Ka and Kb with Kw?
The sum of Ka and Kb equals the auto-dissociation constant for water.
The product of Ka and Kb equals the auto-dissociation constant for water.
The quotient of Ka and Kb equals the auto-dissociation constant for water.
The difference of Ka and Kb equals the auto-dissociation constant for water.
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Answered by
GPT-5 mini
AI
The product: Ka · Kb = Kw.
Reason: For a conjugate acid HA and its conjugate base A–,
Ka = [H3O+][A–]/[HA] and Kb = [OH–][HA]/[A–].
Multiplying cancels [HA] and [A–], giving Ka·Kb = [H3O+][OH–] = Kw.
(Thus pKa + pKb = pKw; at 25 °C pKw ≈ 14.)
Reason: For a conjugate acid HA and its conjugate base A–,
Ka = [H3O+][A–]/[HA] and Kb = [OH–][HA]/[A–].
Multiplying cancels [HA] and [A–], giving Ka·Kb = [H3O+][OH–] = Kw.
(Thus pKa + pKb = pKw; at 25 °C pKw ≈ 14.)
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