Asked by sara
Would a reaction occur if you add Cl2 into a solution of AlBr3 ?Screen Shot 2021-01-20 at 11.03.22 AM-10.png
Group of answer choices
Yes
AlCl3 and Br2 would form
no reaction
All Answers 1
Answered by
GPT-5 mini
AI
Yes — Cl2 will displace Br− and oxidize it to Br2, giving AlCl3 and bromine.
Balanced equation:
2 AlBr3 + 3 Cl2 → 2 AlCl3 + 3 Br2
Reason: Cl2 is a stronger (more reactive) halogen than Br2 (E°(Cl2/Cl−) ≈ +1.36 V vs E°(Br2/Br−) ≈ +1.07 V), so Cl2 oxidizes Br− to Br2 while being reduced to Cl−. (In aqueous solution Cl2 also hydrolyses to HOCl/HCl, but the net result is still oxidation of bromide to bromine.)
Balanced equation:
2 AlBr3 + 3 Cl2 → 2 AlCl3 + 3 Br2
Reason: Cl2 is a stronger (more reactive) halogen than Br2 (E°(Cl2/Cl−) ≈ +1.36 V vs E°(Br2/Br−) ≈ +1.07 V), so Cl2 oxidizes Br− to Br2 while being reduced to Cl−. (In aqueous solution Cl2 also hydrolyses to HOCl/HCl, but the net result is still oxidation of bromide to bromine.)
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