A small amount of sodium hydroxide is added to water. When the chemical reaction reaches equilibrium, the pH is 12. Which statement and conclusion about sodium hydroxide is correct?

the negative log of the concentration of OH- ions is 12. Sodium hydroxide is a strong base
the negative log of the concentration of OH- ions is 12. Sodium hydroxide is a strong acid
the negative log of the concentration of OH- ions is 2. Sodium hydroxide is a strong acid
the negative log of the concentration of OH- ions is 2. Sodium hydroxide is a strong base

1 answer

To analyze the pH and the role of sodium hydroxide in the solution, we can start by determining the concentration of hydroxide ions (\(OH^-\)) from the given pH.

A pH of 12 indicates a basic solution. We can convert pH to pOH using the following relationship: \[ \text{pH} + \text{pOH} = 14 \] So, we can find the pOH: \[ \text{pOH} = 14 - \text{pH} = 14 - 12 = 2 \]

Now, we use the pOH to find the concentration of hydroxide ions: \[ \text{pOH} = -\log[OH^-] \] This implies: \[ 2 = -\log[OH^-] \] Thus, taking the antilog, we have: \[ [OH^-] = 10^{-2} , \text{M} = 0.01 , \text{M} \]

Since sodium hydroxide (NaOH) is a strong base, it completely dissociates in water to produce hydroxide ions. Therefore, we can conclude that sodium hydroxide is indeed a strong base.

Now, looking at the statements provided:

  1. The negative log of the concentration of \(OH^-\) ions is 12. Sodium hydroxide is a strong base. (Incorrect: the pOH is 2, not 12)
  2. The negative log of the concentration of \(OH^-\) ions is 12. Sodium hydroxide is a strong acid. (Incorrect: same reason, plus NaOH is not an acid)
  3. The negative log of the concentration of \(OH^-\) ions is 2. Sodium hydroxide is a strong acid. (Incorrect: NaOH is a base)
  4. The negative log of the concentration of \(OH^-\) ions is 2. Sodium hydroxide is a strong base. (Correct)

Therefore, the correct statement is: The negative log of the concentration of \(OH^-\) ions is 2. Sodium hydroxide is a strong base.