To evaluate the given statements using rational approximations, we can simplify each one:
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\( \sqrt{16} < 4 \): This is false. \( \sqrt{16} = 4 \), so it is not less than 4.
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\( \sqrt{12} < \pi \): Approximating \( \sqrt{12} \approx 3.464 \) and \( \pi \approx 3.14159 \), this statement is also false because \( \sqrt{12} > \pi \).
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\( \sqrt{16} > 4 \): This is false as \( \sqrt{16} = 4\).
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\( \sqrt{12} > \pi \): As calculated above, \( \sqrt{12} \approx 3.464 \) and \( \pi \approx 3.14159\), making this statement true.
Therefore, the correct statement is:
\( \sqrt{12} > \pi \).