To determine the measure of \( AC \), we first analyze the information given. We know that point \( B \) is the midpoint of line segment \( AC \), which means:
\[ AB = BC \]
If \( AB = 22.3 \) millimeters, then because \( BC \) is also equal to \( AB \), we have:
\[ BC = 22.3 \text{ millimeters} \]
To find the total length of \( AC \), we add \( AB \) and \( BC \):
\[ AC = AB + BC = 22.3 \text{ mm} + 22.3 \text{ mm} = 44.6 \text{ millimeters} \]
Thus, the measure of \( AC \) is \( 44.6 \) millimeters.
So, the answer is: The measure of \( AC \) is 44.6 millimeters.