Let \( c \) represent the number of bottles of caramel syrup used last week. According to the information given, Ms. Murray used 8 times as many bottles of chocolate syrup as bottles of caramel syrup. Therefore, we can express this relationship as:
\[ \text{Bottles of chocolate syrup} = 8 \times \text{Bottles of caramel syrup} \]
From the problem, we know that Ms. Murray used 72 bottles of chocolate syrup. So we can set up the equation:
\[ 72 = 8c \]
To find the number of bottles of caramel syrup (\( c \)), we need to solve for \( c \) by dividing both sides of the equation by 8:
\[ c = \frac{72}{8} \]
Calculating the right side gives:
\[ c = 9 \]
Thus, Ms. Murray used \(\boxed{9}\) bottles of caramel syrup last week.